100 is the section width of the tire in millimeters.
90 is the aspect ratio, which is 90% of the section width in this case.
So the tire is 100 mm wide, with sidewalls that are 0.90*100 tall = 90 mm tall
The 19 is the rim size but you already had that figured.
While the tire will fit (provided no interference with the swingarm), it is designed for a wider rim than is on your bike, so the profile of the tire will be distorted slightly. This may reduce traction somewhat, and the center knobs will wear a little faster. That tire will also be slightly heavier, and load the engine a bit more. It won't hurt the bike at all, but the proper size rim would bb better to run it on, or the correct size tire for the rim.