I believe he is talking about thus. I know the early 80's vintage XR500R had the auto-decomp (I learned a hard way), but I don't recall the XR400 having an auto-decomp system . . . but I'm getting old. I'll have to study this further.
whether it has that or not, the cable getting out of adjustment could cause the decomp to open the valves just a skosh, keeping you from building up the necessary compression for starting. Another thing to look at while you're adjusting your valves.
and trust me, valve adjustments on that RFVC head are pretty easy. If you get a manual (clymer or otherwise) it'll walk you through it and you'll wonder how come you didn't do it sooner, it's so easy.